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 Halogenoalkanes are compounds made up of alkanes and halogens. The General formula being CnH2n+1X (X being a halogen atom: one of F, Cl, Br or I)

 

Classifying Halogenolkanes

Much like alcohols, halogenoalkanes can be classified according to their structures, as either primary, secondary or tertiary.

Primary (1°) Halogenoalkane

The carbon which is carrying the halogen atom, is attatched to one other alkyl group

 

 

Eg. 1-Bromopropane

 

 

Secondary (2°) Halogenoalkane

 Eg. 2-Bromo-propanen (even though its a branch, you still need to use the laws of naming alkanes)

Halogen atom is attatched to a carbon atom which is then attatchad to two alkyl groups

 

Tertiary (3°) Halogenoalkane

The halogen atom is attatched to a carbon atom which is bonded to three other alkyl groups

Eg. 2-Methyl-2-ChloroPropane

 

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